Details

Autor(en) / Beteiligte

• He, Miaolu
• Feng, Leihao
• Wang, Jin
• Gao, Yunlong
• Zhang, Weiting
• Nie, Lujie
• Hao, Jiajin
• Wang, Jiaqi
• Miao, Rui
• Wang, Lei

Titel

Zr-BTB nanosheets assist in optimizing the structure of forward osmosis membranes to enhance the lithium concentration performance

Ist Teil von

• Journal of membrane science, 2024-07, Vol.706, p.122963, Article 122963

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2024

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Recently, low-energy forward osmosis (FO) technology has been employed in the lithium concentration stage during the extraction of lithium from brine sources. The interlayer FO membrane is renowned for its exceptional structural characteristics; however, challenges remain in selecting suitable interlayer materials and exploring their control mechanisms on amine monomers. As interlayer materials, traditional 3D nanomaterials are prone to detachment, while traditional 2D materials without micropores can increase the transmission resistance of water molecules. This study introduces a novel FO membrane utilizing Zr-BTB nanosheets with 5.4 Å micropores as the interlayer material. Based on detection and simulation calculations, it was found that the increase in steric hindrance and interaction forces jointly slowed the diffusion of amine monomers in the presence of the Zr-BTB interlayer. This results in a thinner separation layer, facilitating water transport. The interlayer also plays crucial roles in preventing defective pore formation in the separation layer and assisting in intercepting salt ions. The Zr-BTB interlayer membrane exhibited a water flux of 29.14 L m−2 h−1 and a reverse salt flux of 0.16 g m−2 h−1, which are superior to those of many FO membranes reported in the field. The prepared membrane also has excellent performance in lithium concentration applications, and its separation mechanism was explored by MD simulations. [Display omitted] •Zr-BTB nanosheets with micropores are arranged and stacked to form an interlayer.•The presence of an interlayer helps eliminate defective holes in the separation layer.•Spatial hindrance and interaction effects are the main factors that slow down the diffusion rate of MPD.•Zr-BTB interlayer membranes show promising applications in lithium concentration.