Details

Autor(en) / Beteiligte

• Wöhlert, Susanne
• Wriedt, Mario
• Jess, Inke
• Näther, Christian

Titel

Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate

Ist Teil von

• Acta crystallographica. Section E, Structure reports online, 2011-06, Vol.67 (6), p.m695-m695

Ort / Verlag

International Union of Crystallography

Erscheinungsjahr

2011

Beschreibungen/Notizen

• In the crystal structure of the title compound, [CuCl(C5H5N)4][N(CN)2]·2C6H5N, the copper(II) cations are coordinated by one chloride anion and four N-bonded pyridine ligands into discrete complexes. The copper(II) cation shows a square-pyramidal coordination environment, with the chloride anion in the apical position. However, there is one additional chloride anion at 3.0065 (9) Å, leading to a disorted octahedral coordination mode for copper. The copper(II) cation, the chloride ligand and the central N atom of the dicyanamide anion are located on twofold rotation axes. Two pyridine solvent molecules are observed in general positions.