Details

Autor(en) / Beteiligte

• Rajbanshi, Biplab
• Saha, Subhadeep
• Mahato, Beauty
• Roy, Debadrita
• Ghosh, Raja
• Ghosh, Narendra Nath
• Ray, Tanusree
• Roy, Mahendra Nath

Titel

A green approach towards the removal of a water pollutant by encapsulation of HBCDD into cyclodextrins: Combined experimental and theoretical studies

Ist Teil von

• Green Analytical Chemistry, 2024-03, Vol.8, p.100097, Article 100097

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2024

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• •β-CD & HP-β-CD form inclusion complexes with HBCDD.•2D NMR, HRMS and theoretical study confirm the encapsulation process.•SEM images show the morphology of ICs.•Thermal stability was investigated by DSC.•Bio-degradability study by pseudomonas sp. bacteria confirms the degradation of the pollutant. Inclusion complexes of a non-biodegradable water pollutant in hydrophobic cavity of β-cyclodextrin and hydroxypropyl-β-cyclodextrin were prepared and characterized. It revealed the enhancement of its fire resistance property and promoted bio-degradability of the water pollutant molecule. The spectroscopic techniques, 1H NMR, 2D ROESY, HRMS, SEM were employed to establish the inclusion phenomenon. Substantial shifts in IR stretching frequency support the inclusion process. The confirmation about the 1:1 stoichiometry of inclusion complexes was obtained from HRMS measurement. Surface texture properties of the inclusion complexes were studied by SEM and the presence of bromine were proved by EDXS. Thermal stability of the inclusion complexes have been illustrated by DSC. The biodegradability study confirms the conversion of non-biodegradable HBCDD into biodegradable material by encapsulating in the two cyclodextrins, i.e., HBCDD get exposed to the microorganism that makes them biodegradable in nature. Furthermore, our theoretical calculations suggest HBCDD formed stable inclusion complexes with both β-CD and HP-β-CD and is concordant with our experimental observations. [Display omitted]