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Prediction of excess molar volumes of selected binary mixtures from refractive index data
Ist Teil von
Journal of the Serbian Chemical Society, 2014-01, Vol.79 (6), p.707-718
Ort / Verlag
Belgrade: Journal of the Serbian Chemical Society
Erscheinungsjahr
2014
Quelle
Free E-Journal (出版社公開部分のみ)
Beschreibungen/Notizen
The excess molar volumes of twenty two binary mixtures containing various groups of organic compounds: alcohols (ethanol, 1-propanol, 1,2-propanediol, 1,3-propanediol and glycerol), ketone (acetone), ester (butyl lactate), lactAM (N-methyl-2-pyrrolidone), PEGs (PEG 200 and PEG 400) and aromatics (benzene, toluene and pyridine) were predicted from the refractive index data, using three types of equations coupled with several mixing rules for refractive index calculations: the Lorentz–Lorenz, Dale–Gladstone, Eykman, Arago–Biot, Newton and Oster. The obtained results were analysed in terms of the applied equation and mixing rule and the nature of the interactions between the components of the mixtures.