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Combined heat and power plants (CHPPs) allow for significant savings in primary energy resources and a reduction in environmental pollution. Mostly it is carried out using steam turbines. However, in the eighties of the twentieth century, a new promising direction in the development of cogeneration appeared. These are plants operating on the organic Rankine cycle (ORC). An analysis of energy innovations abroad is required for the development and adaptation of this direction to Russian realities. Therefore, an analysis of the energy and environmental efficiency of high-moisture biofuels and biofuel mixtures with high ash content was carried out in boilers operating as part of a CHP using ORC technology and traditional steam turbine plants. Some recommendations for the innovative development of small and medium-scale power generation were proposed.