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Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences
Erscheinungsjahr
2023
Link zum Volltext
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
This is a paper in the field of metallurgical engineering. Organophosphorus class extractant D2EHPA (P204) is very widely used in vanadium extraction. Firstly, the form of vanadium present in the leach solution affects the effect of extraction, V(IV) is mainly stable in solution in the form of VO2+ in a strongly acidic solution; when the pH value gradually increases, V(V) mostly exists in the form of H2V10O28 4- and HV10O28 5-. Secondly, based on the research of organophosphorus extractant P204 in recent years, this paper analyzes the conformational relationship of organophosphorus extractant P204 and finds that the spatial site resistance effect is equally important as a secondary factor compared with the type of phosphoryl adjacent groups, based on the hydrogen bonding effect, the extractant molecules will produce dimers or even multimers between them, thus changing the structure and properties of the extractant molecules. Finally, the progress of the development and application of P204 extractive vanadium