Details

Autor(en) / Beteiligte

• Suzuki, Shiori
• Iwata, Tadahisa

Titel

Selective substitution of long-acyl groups into alcohols of kraft lignin over transesterification using ionic liquid

Ist Teil von

• Journal of wood science, 2021-12, Vol.67 (1), p.1-10, Article 53

Ort / Verlag

Singapore: Springer Singapore

Erscheinungsjahr

2021

Quelle

EZB*

Beschreibungen/Notizen

• Kraft lignin is a valuable aromatic renewable resource that is discharged in large quantities during the kraft pulping process. In this study, kraft lignin derivatives with improved solubility and thermal properties were prepared by a facile chemical modification of the aliphatic hydroxy (R-OH) group in kraft lignin with various ester groups. Kraft lignin was subjected to homogeneous transesterification with vinyl esters as acyl donors using an ionic liquid as a green solvent and catalyst. The selective introduction of acyl groups into the R-OH group was confirmed by nuclear magnetic resonance (NMR) spectroscopy, and it was estimated that approximately 90% of the R-OH group was converted whereas more than 80% of the aromatic hydroxy (Ar-OH) group was retained. The R-OH-selective introduction of long-chain acyl groups of more than six carbons successfully provided superior solubility in common low-boiling solvents, such as chloroform and tetrahydrofuran, and sufficient heat-meltability to be molded into films by hot-pressing. All the kraft lignin derivatives showed high glass transition temperatures of over 100 °C, indicating their potential to be heat-resistant materials. The kraft lignin derivatives, in which only the R-OH group was acylated, retain their inherently rich Ar-OH groups and thus, can be applied as desirable precursors in a wide range of further chemical treatments for functional polymer materials.