Molecules (Basel, Switzerland), 2022-12, Vol.27 (23), p.8480
2022
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- Autor(en) / Beteiligte
- Titel
- Recent Advances in DMSO-Based Direct Synthesis of Heterocycles
- Ist Teil von
- Molecules (Basel, Switzerland), 2022-12, Vol.27 (23), p.8480
- Ort / Verlag
- Switzerland: MDPI AG
- Erscheinungsjahr
- 2022
- Quelle
- Free E-Journal (出版社公開部分のみ）
- Beschreibungen/Notizen
- Besides serving as a low-toxicity, inexpensive and easily accessible solvent, dimethyl sulfoxide (DMSO) has also been extensively used as a versatile reagent for the synthesis of functionalized molecules. Dimethyl sulfoxide can not only be utilized as a carbon source, a sulfur source and an oxygen source, but also be employed as a crucial oxidant enabling various transformations. The past decade has witnessed a large number of impressive achievements on the direct synthesis of heterocycles as well as modifications of heterocyclic compounds by applying DMSO as a reagent. This review summarized the DMSO-based direct heterocycle constructions from 2012 to 2022.
- Sprache
- Englisch
- Identifikatoren
- ISSN: 1420-3049eISSN: 1420-3049DOI: 10.3390/molecules27238480Titel-ID: cdi_doaj_primary_oai_doaj_org_article_906546057b2a4fa38802b6bed6cabd90
- Format
- –
- Schlagworte
- Carbon, Carbon sources, Chemical tests and reagents, cyclization, Dimethyl Sulfoxide, Efficiency, heterocycle, Heterocyclic Compounds, Kornblum oxidation, methyl(methylene)sulfonium, Natural products, Oxidants, Oxidation, Oxidizing agents, Reagents, Review, Solvents, Sulfoxides, Sulfur, Toxicity