Details

Autor(en) / Beteiligte

• Yan, Huan
• Zhao, Xiaoxu
• Guo, Na
• Lyu, Zhiyang
• Du, Yonghua
• Xi, Shibo
• Guo, Rui
• Chen, Cheng
• Chen, Zhongxin
• Liu, Wei
• Yao, Chuanhao
• Li, Jing
• Pennycook, Stephen J.
• Chen, Wei
• Su, Chenliang
• Zhang, Chun
• Lu, Jiong

Titel

Atomic engineering of high-density isolated Co atoms on graphene with proximal-atom controlled reaction selectivity

Ist Teil von

• Nature communications, 2018-08, Vol.9 (1), p.3197-9, Article 3197

Ort / Verlag

London: Nature Publishing Group UK

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Controllable synthesis of single atom catalysts (SACs) with high loading remains challenging due to the aggregation tendency of metal atoms as the surface coverage increases. Here we report the synthesis of graphene supported cobalt SACs (Co 1 /G) with a tuneable high loading by atomic layer deposition. Ozone treatment of the graphene support not only eliminates the undesirable ligands of the pre-deposited metal precursors, but also regenerates active sites for the precise tuning of the density of Co atoms. The Co 1 /G SACs also demonstrate exceptional activity and high selectivity for the hydrogenation of nitroarenes to produce azoxy aromatic compounds, attributable to the formation of a coordinatively unsaturated and positively charged catalytically active center (Co–O–C) arising from the proximal-atom induced partial depletion of the 3 d Co orbitals. Our findings pave the way for the precise engineering of the metal loading in a variety of SACs for superior catalytic activities. Controllable synthesis of single atom catalysts with sufficiently high metal loading remains challenging due to the tendency of agglomeration. Here the authors synthesize a series of stable atomically dispersed cobalt atoms on graphene with high Co loadings via the regeneration of active sites by atomic layer deposition.