Details

Autor(en) / Beteiligte

• Abdelrahim, Ahmed M.
• El-Moghny, Muhammad G. Abd
• Abdelhady, Hosam H.
• Wali, Hager S.
• Gamil, Mariam M.
• Fahmy, Samanta R.
• Abdel-Hamid, Toka M.
• Mohammed, Gehad K.
• Ahmed, Yasmeen A.
• El-Deab, Mohamed S.

Titel

Tailoring a facile electronic and ionic pathway to boost the storage performance of Fe3O4 nanowires as negative electrode for supercapacitor application

Ist Teil von

• Scientific reports, 2024-07, Vol.14 (1), p.16807-14, Article 16807

Ort / Verlag

London: Nature Publishing Group UK

Erscheinungsjahr

2024

Quelle

EZB-FREE-00999 freely available EZB journals

Beschreibungen/Notizen

• Today, high-energy applications are devoted to boosting the storage performance of asymmetric supercapacitors. Importantly, boosting the storage performance of the negative electrodes is a crucial topic. Fe 3 O 4 -based active materials display a promising theoretical storage performance as a negative electrode. Thus, to get a high storage performance of Fe 3 O 4 , it must be tailored to have a higher ionic and electronic conductivity and outstanding stability. Functionalized graphite felt (GF) is an excellent candidate for tailoring Fe 3 O 4 with a facile ionic and electronic pathway. However, the steps of the functionalization of GF are complex and time-consuming as well as the energy loss during this step. Thus, the in-situ functionalization of the GF surface throughout the synthesis of Fe 3 O 4 active materials is proposed herein. Fe 3 O 4 is electrodeposited at the in-situ functionalized GF surface with the crystalline nanowires-like structure as revealed from the various analyses; SEM, TEM, Mapping EDX, XPS, XRD, wettability test, and Raman analysis. Advantageously, the synthetic approach introduces full homogeneous and uniform coverage of the large surface area of the GF. Thus, Fe 3 O 4 nanowires with high ionic and electronic conductivity are characterized by a higher storage performance. Interestingly, Fe 3 O 4 /GF possesses a high specific capacity of 1418 mC cm −2 at a potential scan rate of 10 mV s −1 and this value retained to 54% at a potential scan rate of 50 mV s −1 at an extended potential window of 1.45 V. Remarkably, the diffusion-controlled reaction is the main contributor of the storage of Fe 3 O 4 /GF electrode as revealed by the mechanistic studies.