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This article is concerned with the study of MHD non-Newtonian nanofluid flow over a stretching/shrinking cylinder along with thermal radiation effects. Two-component slip mechanism models, namely Brownian motion and thermophoresis of nanofluid for the mass and energy transportation, developed by Buongiorno, are used. Convective heat transfer and nonuniform magnetic field are retained for the expanding/contracting cylinder. Variable thermal conductivity and heat generation effects along with slip boundary conditions are utilized over the cylinder surface. By utilizing the similarity transformation, these governing partial differential equations are converted into nonlinear ordinary differential equations (ODEs). To obtain numerical results, these ODE’S are solved by the shooting method using MATLAB software. The impact of different parameters like variable thermal conductivity, radiation parameter, magnetic parameter, Prandtl number, Brownian motion parameter, the magnetic parameter, Weissenberg number, the viscosity ratio parameter and mass transfer parameter, on the velocity, temperature and concentration is discussed graphically. Further, the Sherwood number, Nusselt number, the skin friction coefficient are also discussed through figures. It is noted through analysis that the speed of the nanofluid reduces for the higher Weissenberg number and expanding cylinder. For the contracting cylinder, i.e., for the negative unsteadiness parameter, the velocity increases.