Details

Autor(en) / Beteiligte

• Jiang, Feng
• Li, Sijie
• Ge, Peng
• Tang, Honghu
• Khoso, Sultan A
• Zhang, Chenyang
• Yang, Yue
• Hou, Hongshuai
• Hu, Yuehua
• Sun, Wei
• Ji, Xiaobo

Titel

Size-Tunable Natural Mineral-Molybdenite for Lithium-Ion Batteries Toward: Enhanced Storage Capacity and Quicken Ions Transferring

Ist Teil von

• Frontiers in chemistry, 2018-08, Vol.6, p.389-389

Ort / Verlag

Switzerland: Frontiers Media S.A

Erscheinungsjahr

2018

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• Restricted by the dissatisfied capacity of traditional materials, lithium-ion batteries (LIBs) still suffer from the low energy-density. The pursuing of natural electrode resources with high lithium-storage capability has triggered a plenty of activities. Through the hydro-refining process of raw molybdenite ore, containing crushing-grinding, flotation, exfoliation, and gradient centrifugation, 2D molybdenum disulfide (MoS ) with high purity is massively obtained. The effective tailoring process further induce various sizes (5, 2, 1 and 90 nm) of sheets, accompanying with the increasing of active sites and defects. Utilized as LIB anodes, size-tuning could serve crucial roles on the electrochemical properties. Among them, MoS -1 μm delivers an initial charge capacity of 904 mAh g , reaching up to 1,337 mAh g over 125 loops at 0.1 A g . Even at 5.0 A g , a considerable capacity of 682 mAh g is remained. Detailedly analyzing kinetic origins reveals that size-controlling would bring about lowered charge transfer resistance and quicken ions diffusion. The work is anticipated to shed light on the effect of different MoS sheet sizes on Li-capacity ability and provides a promising strategy for the commercial-scale production of natural mineral as high-capacity anodes.