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Crystal structure of catena -poly[bis-(tetra-ethyl-ammonium) [tetra-aqua-tris(μ-dicyanamido-κ 2 N 1 : N 5 )bis(dicyanamido-κ N 1 )di-cobaltate(II)] dicyanamide]
The structure of the title compound, [N(C
H
)
]
[Co
(C
N
)
(H
O)
](C
N
), is a new example of a metal-dicyanamide coordination polymer which exhibits a unique three-dimensional framework of covalently linked Co
chains. All bridging dicyanamide ligands in the title structure are in the
-bridging mode. The anionic Co
-dicyanamide network is templated by tetra-ethyl-ammonium cations residing in a series of channels extending along the
axis where additional non-coordinating dicyanamidate anions are also located. The framework structure is further stabilized by O-H⋯N hydrogen bonding between aqua ligands and dicyanamido ligands or the dicyanamide anion. In addition, C-H⋯N inter-actions are present between the tetra-ethyl-ammonium cations and dicyanamide amide nitro-gen atoms.