Details

Autor(en) / Beteiligte

• Wei, Wei
• Ma, Jie
• Schaab, Jonas
• Brooks, Jason
• Kang, Seogshin
• Whited, Matthew T
• Djurovich, Peter I
• Thompson, Mark E

Titel

A Comparison between Triphenylmethyl and Triphenylsilyl Spirobifluorenyl Hosts: Synthesis, Photophysics and Performance in Phosphorescent Organic Light-Emitting Diodes

Ist Teil von

• Molecules (Basel, Switzerland), 2023-07, Vol.28 (13), p.5241

Ort / Verlag

Switzerland: MDPI AG

Erscheinungsjahr

2023

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• This study presents the synthesis and characterization of two spirobifluorenyl derivatives substituted with either triphenylmethyl ( ) or triphenylsilyl ( ) moieties for use as host materials in phosphorescent organic light-emitting diodes (PHOLED). Both molecules have similar high triplet energies and large energy gaps. Blue Ir(tpz) and green Ir(ppy) phosphorescent devices were fabricated using these materials as hosts. Surprisingly, demonstrated superior charge-transporting ability compared to , despite having similar energies for their valence orbitals. In particular, proved to be a highly effective host for both blue and green devices, resulting in maximum efficiencies of 12.6% for the Ir(tpz) device and 9.6% for the Ir(ppy) device. These results highlight the benefits of appending the triphenylsilyl moiety onto host materials and underscore the importance of considering the morphology of hosts in the design of efficient PHOLEDs.