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Microstructural evolution and performance of carbon fiber-toughened ZrB2 ceramics with SiC or ZrSi2 additive
Ist Teil von
Journal of advanced ceramics, 2018-12, Vol.7 (4), p.343-351
Ort / Verlag
Beijing: Tsinghua University Press
Erscheinungsjahr
2018
Quelle
Free E-Journal (出版社公開部分のみ)
Beschreibungen/Notizen
ZrB
2
–SiC/ZrSi
2
ceramics containing 30 vol% carbon fiber (C
f
) additive were fabricated by hot pressing at low temperature (1500 °C) using submicron ZrB
2
powders, and their microstructural evolution and performance were investigated. The addition of SiC or ZrSi
2
significantly reduced the onset sintering temperature and enhanced the densification of ZrB
2
. ZrB
2
–ZrSi
2
–C
f
showed poor performance owing to the serious fiber degradation, while the fiber degradation was effectively inhibited in ZrB
2
–SiC–C
f
resulting in high fracture toughness, substantial fiber pull-out, and non-brittle fracture mode for such material. The critical thermal shock temperature difference of ZrB
2
–SiC–C
f
was up to 741 °C, significantly higher than those of ZrB
2
–SiC/ZrSi
2
and ZrB
2
–ZrSi
2
–C
f
. Moreover, this composite displayed a good oxidation resistance at 1500 °C in air.