Details

Autor(en) / Beteiligte

• Prasad, R.N.
• Agrawal, M.
• Sharma, M.

Titel

Mixed ligand complexes of alkaline earth metals: Part XII. Mg(II), Ca(II), Sr(II) and Ba(II) complexes with 5-chlorosalicylaldehyde and salicylaldehyde or hydroxyaromatic ketones

Ist Teil von

• Journal of the Serbian Chemical Society, 2002-01, Vol.67 (4), p.229-234

Ort / Verlag

Serbian Chemical Society

Erscheinungsjahr

2002

Link zum Volltext

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• The reactions of alkaline earth metal chlorides with 5-chlorosalicylaldehyde and salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone have been carried out in 1: 1: 1 mole ratio and the mixed ligand complexes of the type MLL?(H2O)2 (where M = Mg(II), Ca(II), Sr(II) and Ba(II),HL= 5-chlorosalicylaldehyde and HL?= salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone) have been isolated. These complexes were characterized by TLC, conductance measurements, IR and 1H-NMR spectra. Proucavane su reakcije zemnoalkalnih hlorida sa 5-hlorosalicilaldehidom i salicilaldehidom, 2-hidroksiacetofenonom ili 2-hidroksipropiofenonom u molskim odnosima 1:1:1 pri cemu su dobijeni kompleksi sa mesovitim ligandima tipa MLL?(H2O)2 (ovde je M= Mg(II), Ca(II), Sr(II) ili Ba(II),HL= 5-hlorosalicilaldehid, aHL? = salicilaldehid, 2-hidroksiacetofenon ili 2-hidroksipropiofenon). Ovi kompleksi su karakterisani pomocu TLC, merenjem provodljivosti, kao i pomocu IR i 1H-NMR spektara.