Details

Autor(en) / Beteiligte

• Sadiq, Muhammad Usman
• Shah, Afzal
• Nisar, Jan
• Shah, Iltaf

Titel

Photoelectrocatalytic Detection and Degradation Studies of a Hazardous Textile Dye Safranin T

Ist Teil von

• Nanomaterials (Basel, Switzerland), 2023-07, Vol.13 (15), p.2218

Ort / Verlag

Switzerland: MDPI AG

Erscheinungsjahr

2023

Quelle

EZB Free E-Journals

Beschreibungen/Notizen

• Herein, we report an electrochemical scaffold consisting of functionalized multiwalled carbon nanotubes (COOH- MWCNTs) and iron-doped zinc oxide nanoparticles (Fe-ZnO) for the detection of a hazardous textile dye safranin T (ST) and monitoring of its photocatalytic degradation. Prior to the detection and degradation analysis, Fe-ZnO NPs were synthesized by the sol-gel method and characterized by a number of structural and morphological techniques. The carboxyl moiety of COOH- MWCNTs possessing a strong affinity for the amino functionality of ST led to significant enhancement of the current response at the designed electrochemical platform, whereas the electrocatalytic role, surface area enhancement, and the provision of binding sites of Fe-ZnO led to a further increase in the peak current intensity of ST. Electrochemical impedance spectroscopy showed that the sensing scaffold made of the glassy carbon electrode modified with COOH- MWCNTs and Fe-ZnO efficiently transfers charge between the transducer and the redox probe. Under optimized conditions, the developed sensor showed a 2.3 nM limit of detection for ST. Moreover, recovery experiments and anti-interference tests qualified the sensing platform for practical applications. The dye was photocatalytically degraded using Fe-ZnO NPs up to 99% in 60 min with a rate constant of 0.068 min . The designed sensor was used to probe the degradation kinetics of the target dye, and the results were found consistent with the findings obtained from electronic absorption method. To the best of our knowledge, the present work is the first approach for the efficient detection and almost absolute degradation of ST.