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Formation of triple alloys and their hydrides in the Ti-Zr-Hf-H system
Ist Teil von
International journal of self-propagating high-temperature synthesis, 2010-03, Vol.19 (1), p.34-39
Ort / Verlag
Heidelberg: Allerton Press, Inc
Erscheinungsjahr
2010
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
A novel technique is suggested for synthesis of refractory metal alloys by dehydrogenation of compacted mixtures of transition metal hydrides. This technique is applicable to preparation of not only binary but also multi-component alloys, intermetallics, and alloys of III, IV, V, and VIII Group metals with various additives. In this work, the results of detailed investigation on the conditions for formation of Ti-Zr-Hf triple alloys from the TiH
2
, ZrH
2
, and HfH
2
are presented. The alloy structure was found to depend on the ratio of components in a green charge. The triple alloys containing the α- and ω-phases have been prepared. Demonstrated was the ability of Ti-Zr-Hf triple alloys to undergo reaction with hydrogen in a combustion mode yielding respective hydrides.