Details

Autor(en) / Beteiligte

• Endres, Helmut
• Bongart, August
• Nöthe, Dietrich

Titel

Average Structure of Bis(oxamide oximato)nickel(II) X Dimethyl-tetracyanoquinodimethane, a “Charge Transfer” Compound with Mixed Stacks and Variable Paramagnetism

Ist Teil von

• Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1986-03, Vol.41 (3), p.334-338

Ort / Verlag

Verlag der Zeitschrift für Naturforschung

Erscheinungsjahr

1986

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The average unit cell of the methanol solvate [Ni(C ] × C × 2CH OH, M = 589.22 is triclinic. Ρ1̄, a = 8.539(3). b = 8.937(3). c = 9.418(3) Å, α = 103.39(3). β = 100.12(2), γ = 105.39(2)°, V = 652.2 Å Z = 1, d = 1.50 gem , final R = 0.050 for 1580 observed independent reflections. Satellite reflections hint at a modulation of the structure in the ac plane. Mixed stacks of alternating and mainly neutral metal complex and Me tcnq molecules are formed. Crystals grown with electrochemical reduction show a weak activated paramagnetism, those grown without electrochemical support are diamagnetic.