Details

Autor(en) / Beteiligte

• Endres, Helmut
• Kadkhodai-Elyaderani, Nasser

Titel

Malonenamidoxim, Nickelkomplexe und deren ßeaktionsprodukte mit Sauerstoff und Kohlendioxid: Vergleichende Strukturuntersuchungen / Malonenamide Oxime, Nickel Complexes, and their Reaction Products with Oxygen and Carbon Dioxide: Comparative Structural Studies

Ist Teil von

• Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1982-10, Vol.37 (10), p.1255-1265

Ort / Verlag

Verlag der Zeitschrift für Naturforschung

Erscheinungsjahr

1982

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Malonenamide oxime [HONC(NH )CH C(NH )NOH = C ] (1), its bis-chelate complex with Ni(II) [Ni(C ] (2) and an ethanol solvate of this complex [Ni(C · 0.6 C OH] (3) are characterized by X-ray structure analysis, as well as a paramagnetic tris-complex [Ni(C (C )] (4), which forms a catena structure in the crystal. The molecular structures of two reaction products of 2 with air are described: [Ni(C (H O) ] · 4 H O (5) has formed by oxidation of the methylene groups and may be taken as a complex of mesoxalamide oxime; [NiC ] · 6 H O (6) has a macrocyclic ligand which is a derivative of orthocarbonic acid, formed by addition of carbon dioxide to the oxime groups.