Details

Autor(en) / Beteiligte

• Larson, Karl
• Carmona, Eric A
• Albertus, Paul

Titel

High Areal Capacity Cycling of Three-Electrode Sodium/NBA/Sodium Cells

Ist Teil von

• Meeting abstracts (Electrochemical Society), 2023-12, Vol.MA2023-02 (5), p.851-851

Erscheinungsjahr

2023

Beschreibungen/Notizen

• The cycling stability of Li and Na metal electrodes is influenced by the interface with the solid electrolyte. Study of the cycling behavior at areal capacities >>0.5 mAh/cm 2 are uncommon, and plating and stripping behaviors remain relatively unknown for the individual electrode/electrolyte interfaces because of the difficulty of separating the individual interfaces in a two-electrode cell configuration. Because areal capacities of practical cells target >5 mAh/cm 2 , it is important to cycle at much higher areal capacities than typically studied. Here, we utilize a three-electrode symmetric cell of sodium metal with sodium beta alumina (NBA) electrolyte and cycled areal capacities ranging from 0.5 to 5 mAh cm -2 and achieved current densities >10 mA cm -2 at 1.0 mAh cm -2 . We find that polarization increases most at the stripping electrode, and that during current density ramps the polarizations are greatly affected by the areal capacity, affecting the maximum current density that can be reached prior to either cell shorting or impedance rise that drives the voltage magnitude to well over 1 V. Additionally, we found resistance rise occurring at the Na/NBA interface during plate (reduction) as well as strip (oxidation) for the same electrode, potentially indicating voiding on plate at sufficiently high current densities and areal capacities (5 mAh cm -2 , >2 mA cm -2 ). For two-electrode studies, the voltage evolution on the plating electrode we observe must be considered for the assumption that the plating electrode is a pseudo reference electrode. We also use our three-electrode cell configuration to study several other experimental conditions, including cycling to failure at a fixed current density and areal capacity, as well as a uni-directional current flow experiment to determine the maximum amount of plating / stripping that can be achieved in the absence of cycling. These findings will help direct future experiments and interpretation of data to quantify the limits and improve the engineering of Li and Na metal / solid electrolytes interfaces. Jolly, D. S.; Ning, Z.; Darnbrough, J. E.; Kasemchainan, J.; Hartley, G. O.; Adamson, P.; Armstrong, D. E. J.; Marrow, J.; Bruce, P. G. Sodium/Na Β″ Alumina Interface: Effect of Pressure on Voids. ACS Appl Mater Interfaces 2019 , 12 (1), 678–685. https://doi.org/10.1021/ACSAMI.9B17786. Krauskopf, T.; Hartmann, H.; Zeier, W. G.; Janek, J. Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries - An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li 6.25 Al 0.25 La 3 Zr 2 O 12. ACS Appl Mater Interfaces 2019 , 11 (15), 14463–14477. https://doi.org/10.1021/ACSAMI.9B02537/SUPPL_FILE/AM9B02537_SI_001.PDF.