Details

Autor(en) / Beteiligte

• Krasil’nikov, M. B.
• Rozhdestvenskiĭ, O. I.
• Smolin, A. G.
• Vasyutinskiĭ, O. S.

Titel

Application of Raman scattering to study of anisotropy of molecular ensembles

Ist Teil von

• Optics and spectroscopy, 2010-10, Vol.109 (4), p.486-492

Ort / Verlag

Dordrecht: SP MAIK Nauka/Interperiodica

Erscheinungsjahr

2010

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A general expression is obtained for the Raman scattering intensity in an ensemble of diatomic molecules for an arbitrary geometry of the experiment as a function of the anisotropy of angular distribution of molecular axes. In its derivation, the irreducible representation of the density matrix of molecules was used. It is shown that, in the Raman scattering experiments on the study of the anisotropy of molecular ensembles, a significant contribution to the signal is made, not only by the second-order terms 〈cos 2 θ〉, but also by the fourth-order terms proportional to 〈cos 4 θ〉, which should be taken into account to correctly interpret the experimental data. Convenient experimental geometries are proposed that allow the anisotropy of a molecular ensemble to be investigated.