Details

Autor(en) / Beteiligte

• Hwang, In‐Chul
• Ha, Kwang

Titel

Diacetato(1,4,8,11‐tetraazacyclotetradecane)manganese(III) perchlorate monohydrate

Ist Teil von

• Acta crystallographica. Section E, Structure reports online, 2007-09, Vol.63 (9), p.m2299-m2299

Ort / Verlag

5 Abbey Square, Chester, Cheshire CH1 2HU, England: Blackwell Publishing Ltd

Erscheinungsjahr

2007

Quelle

Wiley Online Library All Journals

Beschreibungen/Notizen

• The title compound, [Mn(CH3COO)2(C10H24N4)]ClO4·H2O, contains two crystallographically independent cationic complexes, each located with their central MnIII atom on a centre of inversion. Each MnIII atom is six‐coordinated in a distorted octahedral geometry by two O atoms from acetate anions occupying axial positions and four N atoms from 1,4,8,11‐tetraazacyclotetradecane (cyclam) occupying equatorial positions. The compound displays intra‐ and intermolecular N—H...O and O—H...O hydrogen bonding.