Details

Autor(en) / Beteiligte

• Chen, Wen-Xian
• Liu, Qiu-Ping
• Zhuang, Gui-Lin
• Zhou, Sheng-Jun

Titel

A novel La III -based metal–organic framework (MOF) with a new topology: poly[diaquabis(μ 5 -2,5-dioxopiperazine-1,4-diacetato)(μ 2 -oxalato)dilanthanum(III)]

Ist Teil von

• Acta crystallographica. Section C, Crystal structure communications, 2013-01, Vol.69 (1), p.5-7

Erscheinungsjahr

2013

Quelle

Wiley Online Library Journals Frontfile Complete

Beschreibungen/Notizen

• In the title metal–organic framework (MOF), [La(C 8 H 8 N 2 O 6 )(C 2 O 4 ) 0.5 (H 2 O)] n , the La III cation is coordinated by eight O atoms in a square antiprismatic configuration. Each La III cation is connected to adjacent La III cations by bridging 2,5-dioxopiperazine-1,4-diacetate (PODC 2− ) and oxalate (lying about an inversion centre) ligands, generating two-dimensional grid layers. The layers are further linked via the carboxylate groups of the PODC 2− ligands in syn – syn and syn – anti modes, resulting in a three-dimensional framework with a short Schläfli vertex notation of {4 7 .6 3 }{4 7 .6 7 .8}.