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Nowadays, Chemical-Biological-Radiological-Nuclear-explosive (CBRNe) risks are one of the world's main safety concerns. The radiological disasters of Fukushima and Chernobyl, the chemical events of Seveso or the release of Sarin in the Tokyo Subway, the biological emergencies such as the H1N1 flu or the recent Ebola outbreak, and recent news about the availability of non-conventional weapons acquired by fundamentalist organisations represent evidence of potential future threats. CBRNe risks are a real and global threat. The University of Rome, Tor Vergata, in collaboration with the most important Italian and international bodies working in the field of CBRNe safety and security, and supported by the North Atlantic Treaty Organisation and the Organisation for the Prohibition of Chemical Weapons, organises International Masters Courses on the Protection against CBRNe events. Within this framework, a Table-Top Exercise was planned, in collaboration with the Italian Ministry of Interior and Ministry of Defence. The scenario, the logistic organisation, on-going adjustments during the exercise and the outcomes are presented here and analysed.