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The focus of this study is a new lifetime distribution with five parameters created by combining the Weibull–Burr XII model and the Marshall–Olkin-G family. The newly suggested model is known as the Marshall–Olkin Weibull–Burr XII (MOWBXII) distribution. The new distribution has the benefit of being able to model different types of data, and it is useful in reliability and lifespan statistics. Several current distributions as well as new distributions are included in the MOWBXII distribution. The MOWBXII density function is represented as a linear combination of Burr XII densities. Some statistical properties of the MOWBXII distribution are discussed. Various techniques for estimating the model’s parameters are used. The proposed estimation methods are weighted least squares, maximum likelihood, least squares, and maximum product of spacing methods. The effectiveness of different estimates is evaluated in terms of relative bias and mean squared error of the simulation study. Practical illustrations of the MOWBXII distribution are demonstrated using two real datasets. Furthermore, it is shown that the proposed distribution fits well, and this is claimed by comparing with Burr XII-based distributions and some other distributions by means of some measures of goodness-of-fit.