Details

Autor(en) / Beteiligte

• Cheung, A. S.-C.
• Mok, D. K.-W.
• Jamieson, M. J.
• Finch, M.
• Yoshino, K.
• Dalgarno, A.
• Parkinson, W. H.

Titel

Rotational dependence of the predissociation linewidths of the Schumann-Runge bands of O2

Ist Teil von

• The Journal of chemical physics, 1993-07, Vol.99 (2), p.1086-1092

Ort / Verlag

Legacy CDMS: American Institute of Physics

Erscheinungsjahr

1993

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The rotational coupling constant for the O2 molecule is estimated theoretically, and the predissociation linewidths of the Schumann-Runge bands of vibration levels v = 0-12 are calculated for (O-16)2, (O-16)(O-18), and (O-18)2 molecules in the B 3Sigma-u(-) state. Calculations accounted for both the spin-orbit and rotational couplings with rotational quantum number N up to 20. The theoretical linewidths are compared with experimental widths, showing satisfactory agreement.