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Recombination contacts play an important role in highly efficient organic tandem solar cells. We present a photoelectron spectroscopy study on contact systems that have previously been shown to work efficiently as recombination contacts. Here, the conversion of an electron current into a hole current is realized either by insertion of gold clusters or by a highly doped pn-junction. From the measured energy level alignments, we show that the working principles of these two approaches are significantly different. For gold clusters, the recombination current is promoted by an accumulation of charge carriers, while for doped pn-junctions, it is achieved by tunneling through a depletion layer.
Sprache
Englisch
Identifikatoren
ISSN: 0003-6951
eISSN: 1077-3118
DOI: 10.1063/1.3693385
Titel-ID: cdi_crossref_primary_10_1063_1_3693385
Format
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