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Graphene is a hexagonally bonded sheet of carbon atoms that exhibits superior transport properties with a velocity of
10
8
cm
∕
s
and a room-temperature mobility of
>
15
000
cm
2
∕
V
s
. How to grow gate dielectrics on graphene with low defect states is a challenge for graphene-based nanoelectronics. Here, we present the growth behavior of
Al
2
O
3
and
Hf
O
2
films on highly ordered pyrolytic graphite (HOPG) by atomic layer deposition (ALD). To our surprise, large numbers of
Al
2
O
3
and
Hf
O
2
nanoribbons, with dimensions of
5
-
200
nm
in width and
>
50
μ
m
in length, are observed on HOPG surfaces at growth temperature between 200 and
250
°
C
. This is due to the large numbers of step edges of graphene on HOPG surfaces, which serve as nucleation sites for the ALD process. These
Al
2
O
3
and
Hf
O
2
nanoribbons can be used as hard masks to generate graphene nanoribbons or as top-gate dielectrics for graphene devices. This methodology could be extended to synthesize insulating, semiconducting, and metallic nanostructures and their combinations.
Sprache
Englisch
Identifikatoren
ISSN: 0003-6951
eISSN: 1077-3118
DOI: 10.1063/1.2828338
Titel-ID: cdi_crossref_primary_10_1063_1_2828338
Format
–
Weiterführende Literatur
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