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A new benzimidazole/carbazole hybrid bipolar material for highly efficient deep-blue electrofluorescence, yellow-green electrophosphorescence, and two-color-based white OLEDs
Ist Teil von
Journal of materials chemistry, 2010-01, Vol.2 (45), p.1113-1119
Erscheinungsjahr
2010
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
The bipolar molecule
CPhBzIm
exhibits an excellent solid state photoluminescence quantum yield (
Φ
PL
= 69%), triplet energy (
E
T
= 2.48 eV), and bipolar charge transport ability (
μ
h
μ
e
10
−6
-10
−5
cm
2
V
−1
s
−1
). We have used it to fabricate a non-doped deep-blue organic light emitting diode (OLED) exhibiting promising performance [
η
ext
= 3%; CIE = (0.16, 0.05)] and to serve as host material for a yellow-green phosphorescent OLED [
η
ext
= 19.2%; CIE = (0.42, 0.56)]. Exploiting these dual roles, we used
CPhBzIm
in a simple singly doped, two-color-based white OLED (
η
ext
= 7%; CIE = 0.31, 0.33).
A simple singly doped, two-color-based white OLED was achieved by exploiting the dual roles of
CPhBzIm
as a deep-blue emitter and a host material for Ir-based yellow-green phosphorescence.