Details

Autor(en) / Beteiligte

• Zhang, Ya-Qiong
• Zhang, Yu
• Zeng, Guoping
• Liao, Rong-Zhen
• Li, Man

Titel

Mechanism of photocatalytic CO 2 reduction to HCO 2 H by a robust multifunctional iridium complex

Ist Teil von

• Dalton transactions : an international journal of inorganic chemistry, 2024-01, Vol.53 (2), p.684-698

Ort / Verlag

England

Erscheinungsjahr

2024

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The tetradentate PNNP-type Ir complex Mes-IrPCY2 ([Cl-Ir -H] ) is reported to be an efficient catalyst for the reduction of CO to formate with excellent selectivity under visible light irradiation. Density functional calculations have been carried out to elucidate the mechanism and the origin of selectivity in the present work. Calculations suggest that the double-reduced complex 1-H ( [Ir -H] ) demonstrates higher activity than the single-reduced complex 2-H ( [Ir (L˙ )-H] ), possibly owing to the higher hydride donor ability of the former compared to the latter; thus 1-H functions as the active species in the overall CO reduction reaction. In the HCOO formation pathway, the hydride of 1-H performs a nucleophilic attack on CO an outer-sphere fashion to generate species 1-OCHO ( [Ir -OCHO] ), which then releases HCOO to produce an Ir intermediate. A subsequent protonation and chloride coordination of the Ir center leads to the regeneration of catalyst [Cl-Ir -H] . For the CO production, a nucleophilic attack on CO takes place by the Ir atom of 1-H an inner-sphere manner to afford complex O2C-3-H ( [O C-Ir -H] ), followed by a two-proton-one-electron reduction to furnish the OC-2-H complex ( [OC-Ir (L˙ )-H] ) after liberating a H O. Ultimately, CO is released to form 2-H. The stronger nucleophilicity as well as smaller steric hindrance of the hydride than the Ir atom of the active species 1-H ( [Ir -H] ) is found to account for the favoring of formate formation over CO formation. Meanwhile, the CO reduction reaction is calculated to be preferred over the hydrogen evolution reaction, and this is consistent with the experimental product distributions.