Details

Autor(en) / Beteiligte

• Ma, Fa-Xue
• Mi, Fu-Qi
• Sun, Meng-Jiao
• Huang, Tao
• Wang, Zi-An
• Zhang, Teng
• Cao, Rong

Titel

A highly stable Zn 9 -pyrazolate metal–organic framework with metallosalen ligands as a carbon dioxide cycloaddition catalyst

Ist Teil von

• Inorganic chemistry frontiers, 2022-04, Vol.9 (8), p.1812-1818

Erscheinungsjahr

2022

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A three-dimensional (3D) metal–organic framework constructed from unprecedented Zn 9 O 2 (OH) 2 (pyz) 12 (pyz = pyrazolate) clusters and Ni(salen)-derived linkers was reported. The MOF exhibits high catalytic activity for CO 2 cycloaddition reactions with excellent stability. The MOF catalyst can be recycled at least 15 times without loss of activity and the turnover number (TON) per Ni site can reach as high as 2887.