Details

Autor(en) / Beteiligte

• Huchenski, Blake S. N
• Speed, Alexander W. H

Titel

Room-temperature reduction of sulfur hexafluoride with metal phosphides

Ist Teil von

• Chemical communications (Cambridge, England), 2021-07, Vol.57 (58), p.7128-7131

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Upon treatment with sulfur hexafluoride, alkali metal diphenyl or dicyclohexyl phosphides are oxidized within seconds to tetraphenyl or tetracyclohexyl diphosphines. When bulky di- tert -butylphosphide is employed, fluorophosphine intermediates are detected. This is the first reported reaction of sulfur hexafluoride with metal phosphides, and a rare example of reactivity of sulfur hexafluoride at ambient temperature. Upon treatment with sulfur hexafluoride, alkali metal diphenyl or dicyclohexyl phosphides are oxidized within seconds to tetraphenyl or tetracyclohexyl diphosphines. This is a rare example of reactivity of sulfur hexafluoride at ambient temperature.