Details

Autor(en) / Beteiligte

• Kolokoto, T
• Mashindi, V
• Kadzutu-Sithole, R
• Machogo-Phao, Lerato F E
• Ndala, Z B
• Shumbula, N P
• Nkabinde, S S
• Ngubeni, G N
• Gqoba, S S
• Mubiayi, K P
• Moloto, N

Titel

The effect of the metal and selenium precursors on the properties of NbSe 2 and Nb 2 Se 9 nanostructures and their application in dye-sensitized solar cells

Ist Teil von

• RSC advances, 2021-09, Vol.11 (50), p.31159-31173

Ort / Verlag

England

Erscheinungsjahr

2021

Quelle

EZB Electronic Journals Library

Beschreibungen/Notizen

• Herein, we report on the effect of the precursors on the structural, morphological, and optical properties of niobium selenide using the heat-up colloidal method. The metal precursor was varied from the conventional NbCl to NbF whilst Se, SeO , and selenourea were used as the selenium precursors. The NbCl and NbF resulted in the formation of NbSe and Nb Se respectively. While maintaining the two different metal precursors and varying the selenium precursor from Se, SeO to selenourea, the properties of NbSe and Nb Se changed slightly, however the effect of changing the selenium precursor was less pronounced than changing the metal precursors. From the XRD and XPS, the NbSe nanostructures were more susceptible to oxidation than Nb Se as Nb O was observed in the XRD and the percentage of M-O in the XPS was much higher in NbSe . NbSe formed nanoflowers whilst Nb Se formed rods with 3.29 eV and 2.43 eV band-gaps, respectively. Also, the band-gaps were red-shifted as the selenium precursors were varied. The NbSe nanoflowers and Nb Se nanorods were used as counter electrodes in dye-sensitized solar cells. Two methods were used to fabricate the counter electrodes spin coating and drop casting. The electrochemical properties of the spin coated counter electrodes were better than the drop casted ones; hence, they were employed in dye-sensitized solar cells. The spin coated NbSe nanoflowers had the highest efficiency of 6.84%, attributed to the nanoflower morphology.