Details

Autor(en) / Beteiligte

• Ai, Chongren
• Shen, Haiwei
• Song, Dingguo
• Li, Yujin
• Yi, Xiao
• Wang, Ze
• Ling, Fei
• Zhong, Weihui

Titel

Metal- and oxidant-free electrochemical synthesis of sulfinic esters from thiols and alcohols

Ist Teil von

• Green chemistry : an international journal and green chemistry resource : GC, 2019, Vol.21 (2), p.5528-5531

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2019

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• An efficient and eco-friendly electrochemical synthesis of various sulfinic esters from thiols and alcohols via sequential S-H/S bond cleavage and double S-O bond formation under mild reaction conditions has been developed. Stoichiometric oxidants, metal catalysts, activating agents and even added bases were avoided in this method, and the only by-product generated from this reaction was dihydrogen gas which could serve as a green source of energy. Various functional groups are compatible with this green protocol which can be easily conducted on a gram-scale. An eco-friendly electrochemical synthesis of sulfinic esters from thiols and alcohols under mild reaction conditions has been developed.