Details

Autor(en) / Beteiligte

• Kong, Xiao
• Zhu, Yifeng
• Fang, Zhen
• Kozinski, Janusz A
• Butler, Ian S
• Xu, Lujiang
• Song, He
• Wei, Xiaojie

Titel

Catalytic conversion of 5-hydroxymethylfurfural to some value-added derivatives

Ist Teil von

• Green chemistry : an international journal and green chemistry resource : GC, 2018, Vol.2 (16), p.3657-3682

Ort / Verlag

Cambridge: Royal Society of Chemistry

Erscheinungsjahr

2018

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• 5-Hydroxymethylfurfural (HMF) is a platform chemical derived from C6 sugars, which can be transformed into various important chemicals and fuels because of the presence of C&z.dbd;O, C-O and furan ring functional groups. In this review, the selective tailoring of these groups in HMF to form 2,5-dimethylfuran, 2,5-dihydromethylfuran, 2,5-dihydromethyltetrahydrofuran, 5-ethoxymethylfurfural, 1,6-hexanediol, long-chain alkanes, 3-(hydroxy-methyl)cyclopentanone, p -xylene, 2,5-diformylfuran, 2,5-furandicarboxylic acid and maleic anhydride will be described to gain more insight into the transformation of HMF under various conditions. The focus of this review is on the mechanisms of the catalytic processes and potential design strategies for future catalysts. The activation of the functional groups and the key challenges involved in the precise design of bifunctional catalysts are highlighted. Some examples of "one-pot" transformations of fructose into various chemicals using the HMF platform are also presented. The catalytic mechanisms and catalyst design strategies for 5-hydroxymethylfural conversion are summarized.