Details

Autor(en) / Beteiligte

• Lewis, James E. M
• Galli, Marzia
• Goldup, Stephen M

Titel

Properties and emerging applications of mechanically interlocked ligands

Ist Teil von

• Chemical communications (Cambridge, England), 2017, Vol.53 (2), p.298-312

Ort / Verlag

England

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Mechanically interlocked molecules have a long and rich history as ligands thanks to the key role coordination chemistry has played in the development of high yielding passive template syntheses of rotaxanes and catenanes. In this Feature Article, we highlight the effect of the mechanical bond on the properties of metal ions bound within the sterically hindered environment of the macrocycle cavity, and discuss the emerging applications of interlocked ligands in catalysis, sensing and supramolecular materials. We discuss the properties and potential future applications in catalysis, sensing and materials of ligands based on mechanically interlocked molecules.