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Modeling the voltage loss mechanisms in lithium-sulfur cells: the importance of electrolyte resistance and precipitation kinetics
Ist Teil von
Physical chemistry chemical physics : PCCP, 2015-01, Vol.17 (35), p.22581-22586
Ort / Verlag
England
Erscheinungsjahr
2015
Quelle
Alma/SFX Local Collection
Beschreibungen/Notizen
Understanding of the complex electrochemical, transport, and phase-change phenomena in Li-S cells requires experimental characterization in tandem with mechanistic modeling. However, existing Li-S models currently contradict some key features of experimental findings, particularly the evolution of cell resistance during discharge. We demonstrate that, by introducing a concentration-dependent electrolyte conductivity, the correct trends in voltage drop due to electrolyte resistance and activation overpotentials are retrieved. In addition, we reveal the existence of an often overlooked potential drop mechanism in the low voltage-plateau which originates from the limited rate of Li
2
S precipitation.
We analyse the evolution of three major voltage-drop mechanisms in Li-S cells during discharge, with a particular emphasize on the importance of precipitation-induced variations in the electrolyte resistance and reaction potentials.