Details

Autor(en) / Beteiligte

• Ferguson, George
• Gallagher, John F
• McAlees, Alan J
• McCrindle, Robert

Titel

Mechanism and Stereochemistry of the Reaction of Dichloroplatinum(II) Complexes with Diazo Compounds. X-ray Structures of Four Key Products:  [(2R,3R)-Bis(diphenylphosphino)butane]chloro- [(S)-chloro(methoxycarbonyl)methyl]platinum(II), (η4-1,5-Cyclooctadiene)[3-chloro-5-(dimethoxyphosphonyl)-2- methoxy-4,1,2-platinaoxaphospholane P-oxide], (R,R)-[Chloro(dimethoxyphosphonyl)methyl][chloro- (trimethylsilyl)methyl](1,5-cyclooctadiene)platinum(II), and Chloro[chloro(dimethoxyphosphonyl)methyl](η4-1

Ist Teil von

• Organometallics, 1997-03, Vol.16 (5), p.1053-1057

Ort / Verlag

American Chemical Society

Erscheinungsjahr

1997

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The structures of four key products formed by reaction of diazo compounds of the type RCHN2 (R = CO2Me, P(O)(OMe)2, SiMe3) with chloroplatinum(II) derivatives have been elucidated by X-ray crystallographic methods. The results confirm our earlier conclusions, based on NMR evidence and mechanistic considerations, concerning the stereochemistries of these products.