Details

Autor(en) / Beteiligte

• Chakraborty, Debashis
• Chen, Eugene Y.-X

Titel

First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes

Ist Teil von

• Organometallics, 2003-01, Vol.22 (1), p.207-210

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2003

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The structurally characterized (C6F5)3Al·OH2 (1) and (C6F5)3Al·OHCH3 (2) exhibit medium-strong intermolecular and weak intramolecular O−H···FC hydrogen bonds in the solid state. Both complexes have substantial stability in toluene solutions at room temperature, while the spectroscopic data of 1 show strong activation of the weak Brønsted acid H2O by Al(C6F5)3.