Details

Autor(en) / Beteiligte

• Comins, Daniel L
• Fulp, Alan B

Titel

Enantiopure N-Acyldihydropyridones as Synthetic Intermediates:  Asymmetric Synthesis of (−)-Slaframine

Ist Teil von

• Organic letters, 1999-12, Vol.1 (12), p.1941-1943

Ort / Verlag

United States: American Chemical Society

Erscheinungsjahr

1999

Quelle

MEDLINE

Beschreibungen/Notizen

• An asymmetric synthesis of (−)-slaframine and N-acetylslaframine has been accomplished starting from an enantiopure dihydropyridone building block. The oxygen−carbon bond at C-1 was incorporated with complete stereoselectivity by using an efficient phenylselenocyclocarbamation reaction.