Details

Autor(en) / Beteiligte

• Bundgaard, Eva
• Krebs, Frederik C

Titel

Low-Band-Gap Conjugated Polymers Based on Thiophene, Benzothiadiazole, and Benzobis(thiadiazole)

Ist Teil von

• Macromolecules, 2006-04, Vol.39 (8), p.2823-2831

Ort / Verlag

Washington, DC: American Chemical Society

Erscheinungsjahr

2006

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A series of low-band-gap copolymers of thiophene, benzothiadiazole, and benzobis(thiadiazole) were synthesized. The polymers were synthesized by Stille cross-coupling polymerization of distannylalkylthiophenes and dithiophenes with dibromo derivatives of benzothiadiazoles and benzobis(thiadiazole)s. The polymers were characterized using NMR, UV−vis, and size exclusion chromatography (SEC). The molecular weight, solubility, and film-forming ability were highly dependent on the choice of side chains. 3,7,11-Trimethyldodecyl side chains were found to give polymer products with high molecular weight, good film-forming ability, and good solubility. Band gaps were estimated from UV−vis to be 2.1−1.7 eV for polymers based on benzothiadiazole and ∼0.7 eV for polymers based on benzobis(thiadiazole). The band gap and electronic structure of the polymers were determined by a combination of UV−vis spectroscopy and ultraviolet photoelectron spectroscopy (UPS).