Details

Autor(en) / Beteiligte

• Oganesyan, Vasily S
• Cammidge, Andrew N
• Hopkins, Gareth A
• Cotterill, Fiona M
• Reid, Ivan D
• Jayasooriya, Upali A

Titel

Muon Spin Rotation Studies of Enediynes

Ist Teil von

• The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2004-03, Vol.108 (10), p.1860-1866

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2004

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RC⋮CCHCHC⋮CR where R = −CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.