Details

Autor(en) / Beteiligte

• Xu, Fan
• Li, Yan-Jie
• Huang, Chong
• Xu, Hai-Chao

Titel

Ruthenium-Catalyzed Electrochemical Dehydrogenative Alkyne Annulation

Ist Teil von

• ACS catalysis, 2018-05, Vol.8 (5), p.3820-3824

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2018

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• A ruthenium-catalyzed electrochemical dehydrogenative annulation reaction of aniline derivatives and alkynes has been developed for the synthesis of indoles. Electric current is used to recycle the active ruthenium-based catalyst and promote H2 evolution. The electrolysis reaction is operationally convenient as it employs a simple undivided cell, proceeds efficiently in an aqueous solution, and is insensitive to air.