Details

Autor(en) / Beteiligte

• Laptev, Vladimir B
• Kompanets, Victor O
• Pigulsky, Sergey V
• Makarov, Alexander A
• Mishakov, Gennadii V
• Serebryakov, Dmitry V
• Sharkov, Andrey V
• Chekalin, Sergey V
• Ryabov, Evgeny A

Titel

IVR Dynamics of Vibrational Levels of the ν 1 Mode in (CF 3 ) 2 C═C═O Molecules Excited by Resonant IR Femtosecond Radiation

Ist Teil von

• The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2019-01, Vol.123 (4), p.771-779

Ort / Verlag

United States

Erscheinungsjahr

2019

Link zum Volltext

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• The intramolecular dynamics of vibrational levels (up to v = 5) of the ν mode in the (CF ) CCO molecule that is induced by a multiphoton selective excitation of this mode by resonant femtosecond IR radiation has been studied. The times of intramolecular vibrational energy redistribution (IVR) from each vibrational level to remaining molecular modes have been determined. In accordance with theoretical predictions, a decrease in the IVR time with increasing quantum number v has been observed for the first time. A sharp decrease in the IVR time (down to 1.5 ps) at a wavelength of 2129 cm , corresponding to the v = 3 → v = 4 vibrational transition, is revealed. It has been shown that, with a negative chirp of a femtosecond radiation pulse, the population of high-lying vibrational levels of the ν mode increases significantly.