Details

Autor(en) / Beteiligte

• Corpinot, Mérina K
• Guo, Rui
• Tocher, Derek A
• Buanz, Asma B. M
• Gaisford, Simon
• Price, Sarah L
• Bučar, Dejan-Krešimir

Titel

Are Oxygen and Sulfur Atoms Structurally Equivalent in Organic Crystals?

Ist Teil von

• Crystal growth & design, 2017-02, Vol.17 (2), p.827-833

Ort / Verlag

American Chemical Society

Erscheinungsjahr

2017

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• New guidelines for the design of structurally equivalent molecular crystals were derived from structural analyses of new cocrystals and polymorphs of saccharin and thiosaccharin, aided by a computational study. The study shows that isostructural crystals may be obtained through an exchange of >CO with >CS in the molecular components of the solids, but only if the exchanged atom is not involved in hydrogen bonding.