Details

Autor(en) / Beteiligte

• Yang, Yiwen
• Ma, Hongxia

Titel

Room-temperature direct benzylic oxidation catalyzed by cobalt(II) perchlorate

Ist Teil von

• Tetrahedron letters, 2016-11, Vol.57 (47), p.5278-5280

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2016

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• [Display omitted] •12 aromatic ketones were obtained by the direct benzylic oxidation.•The oxidation can proceed at room temperature and it takes only 3h.•It employs Co(ClO4)2 as catalyst and oxone as oxidant. Aromatic ketones were synthesized from alkylbenzene derivatives through a novel method that employs cobalt(II) perchlorate as catalyst and oxone as oxidant. The reaction smoothly proceeded at room temperature with yields reaching 96%.