Details

Autor(en) / Beteiligte

• Liu, Cheng-Hang
• Xu, Mengyang
• Luo, Qiyun
• Wang, Ziyan
• Tan, Wenyue
• Zhao, Xingzeng
• Jia, Xiaodong

Titel

Inexpensive and mild hydrogenation condition: Raney Ni-catalyzed reduction of alkenes and alkynes using Et3SiH at ambient temperature

Ist Teil von

• Tetrahedron, 2024-06, Vol.160, p.134040, Article 134040

Ort / Verlag

Elsevier Ltd

Erscheinungsjahr

2024

Quelle

Access via ScienceDirect (Elsevier)

Beschreibungen/Notizen

• The Raney Ni-catalyzed hydrogenation of alkenes and alkynes has been developed. Et3SiH was chosen as the reductant. Substrates with various substituents were reduced at ambient temperature, affording good to excellent yields. No pressure reactor, heating, or inert atmosphere is required and the catalyst can be removed/recycled by simple filtration. Raney Ni-catalyzed hydrogenation of alkenes and alkynes using Et3SiH as the reductant at ambient temperature. [Display omitted]