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Details

Autor(en) / Beteiligte
Titel
Testing the performance of one and two box models as tools for risk assessment of particle exposure during packing of inorganic fertilizer
Ist Teil von
  • The Science of the total environment, 2019-02, Vol.650 (Pt 2), p.2423-2436
Ort / Verlag
Netherlands: Elsevier B.V
Erscheinungsjahr
2019
Link zum Volltext
Quelle
MEDLINE
Beschreibungen/Notizen
  • Modelling of particle exposure is a useful tool for preliminary exposure assessment in workplaces with low and high exposure concentrations. However, actual exposure measurements are needed to assess models reliability. Worker exposure was monitored during packing of an inorganic granulate fertilizer at industrial scale using small and big bags. Particle concentrations were modelled with one and two box models, where the emission source was estimated with the fertilizer's dustiness index. The exposure levels were used to calculate inhaled dose rates and test accuracy of the exposure modellings. The particle number concentrations were measured from worker area by using a mobility and optical particle sizer which were used to calculate surface area and mass concentrations. The concentrations in the worker area during pre-activity ranged 63,797–81,073 cm−3, 4.6 × 106 to 7.5 × 106 μm2 cm−3, and 354 to 634 μg m−3 (respirable mass fraction) and during packing 50,300 to 85,949 cm−3, 4.3 × 106 to 7.6 × 106 μm2 cm−3, and 279 to 668 μg m−3 (respirable mass fraction). Thus, the packing process did not significantly increase the exposure levels. Chemical exposure was also under control based on REACH standards. The particle surface area deposition rate in respiratory tract was up to 7.6 × 106 μm2 min−1 during packing, with 52%–61% of deposition occurring in the alveolar region. Ratios of the modelled and measured concentrations were 0.98 ± 0.19 and 0.84 ± 0.12 for small and big bags, respectively, when using the one box model, and 0.88 ± 0.25 and 0.82 ± 0.12, when using the two box model. The modelling precision improved for both models when outdoor particle concentrations were included. This study shows that exposure concentrations in a low emission industrial scenario, e.g. during packing of a fertilizer, can be predicted with a reasonable accuracy by using the concept of dustiness and mass balance models. [Display omitted] •Occupational exposure to particles during industrial packing was assessed.•No significant increases were found during packing of a granulate fertilizer.•One and two box models predicted adequately actual worker exposure.•Including outdoor concentrations in models was seen to improve their performance.•Models parametrization was seen to be a key issue to adequately predict exposure.

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