Details

Autor(en) / Beteiligte

• Kulawik, Sebastian
• Gierlotka, Wojciech
• Dębski, Adam
• Gąsior, Władysław
• Zajączkowski, Andrzej

Titel

Calorimetric and phase diagram studies of the Ga-In-Zn system

Ist Teil von

• Journal of molecular liquids, 2021-03, Vol.325, p.115114, Article 115114

Ort / Verlag

Elsevier B.V

Erscheinungsjahr

2021

Quelle

Alma/SFX Local Collection

Beschreibungen/Notizen

• Partial and integral enthalpies of mixing of liquid Ga-In-Zn alloys at a temperature of 720 K were measured by high-temperature drop calorimetry. Calorimetric measurements were performed along four intersections as follows: xGa/xZn = 3/1, xGa/xZn = 1/1, xGa/xZn = 1/3 and xGa/xIn =1/3. Based on obtained thermodynamic results and those available in the literature the thermodynamic optimization was done using Thermo-Calc software. Next, the phase equilibria in the binary and ternary systems were calculated and the results were compared with those obtained using different experimental techniques. •The integral molar mixing enthalpy of liquid ternary Ga-In-Zn alloys has been investigated.•Four intersections: xGa/xZn = 3/1, xGa/xZn = 1/1, xGa/xZn = 1/3 and xGa/xIn = 1/3 were investigated.•Thermodynamic model of Ga-In-Zn system was obtained.